Personally, I'd turn Daniels into an uppercard heel. He could feud with Killings, and possibly even Raven down the line. He's got the mic skills too.
As for Skipper, I think he'd fit in well as a midcarding face. Being the weaker half of the team, both with in-ring ability and mic skills, I wouldn't want Skipper to receive too big of a push. He's got the moveset of a face, and I think he'd fit in well, receiving X-Title shots every once in awhile.
Daniels will probably work feuds with people like DDP or A.J. Styles, someone in the mid/upper-mid card.
Skipper I can see fitting well in the X-Division. He's not too flashy, but has some cool moves.
Daniels should be pushed to the moon. He's a guy that TNA could seriously push and claims as one of their own stars. He gets over everywhere he goes.
I think the problem with a major push to the main event is because of his Japanese tours every now and then. Not as many as Low-Ki does, but still a substantial amount IIRC.